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Mimicking the Silicon Surface: Reactivity of Silyl Radical Cations toward Nucleophiles

✍ Scribed by Rijksen, Bart; van Lagen, Barend; Zuilhof, Han


Book ID
127000925
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
789 KB
Volume
133
Category
Article
ISSN
0002-7863

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For correlating a homoconjugation structure of a radical cation to its reactivity with a nucleophile, the reactivity and rr-facial selectivity of CH3OH and H20 addition to the radical cations of 7-benzhydrylidenenorbornene derivatives generated by photoinduced electron transfer reactions were invest