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Millimeter-Wave Spectrum of As35Cl3: Observation of theK= 3 Line Splitting and Determination of the Chlorine Quadrupole Coupling Constant

✍ Scribed by L. Dore; G. Cotti; C.Degli Esposti; G. Cazzoli; J.M. Colmont

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 328 KB
Volume: 174
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1995.0017

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✦ Synopsis

The ground state rotational spectrum of As 35 Cl 3 was investigated in the range 120-376 GHz, and sextic-level spectroscopic constants were determined. A careful analysis of the observed splittings allowed the determination of the h 3 splitting constant, of the arsenic electric and magnetic hyperfine constants, and, notably, of the chlorine quadrupole coupling constant.

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