Mild reductions of oxides of the Group 6a elements sulfur, selenium, and tellurium with (phenylseleno)trimethylsilane
β Scribed by Detty, Michael R.
- Book ID
- 115488903
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 465 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract The lithiated anions of Ξ±βaminoβsubstituted diphenylphosphine oxides 1, in which R can be hydrogen, aryl, alkyl and alkenyl, react with two equivalents of sulfur or selenium to form thioβ and selenoamides, which can be isolated in good to excellent yields in most cases. The optimal reac
AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c