✦ LIBER ✦

Examination of the reactivity of bis(trifluoromethyl)tellurium: oxidative trifluoromethylations and ligand exchanges with Group 5A and 6A (15 and 16) elements and their halides

✍ Scribed by Ganja, E. A.; Morrison, J. A.

Book ID: 127111401
Publisher: American Chemical Society
Year: 1990
Tongue: English
Weight: 861 KB
Volume: 29
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00326a008

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Preparation of bis(trifluoromethyl)tellu

Preparation of bis(trifluoromethyl)tellurium, bis(trifluoromethyl)selenium, bis(trifluoromethyl)diselenium, tris(trifluoromethyl)antimony, tris(trifluoromethyl)arsine, bis(trifluoromethyl)arsenic iodide, tris(trifluoromethyl)phosphine, and (trifluoromethyl)phosphorus diiodide by reaction of bis(trifluoromethyl)mercury with the Group 5 and 6A (15 and 16) halides

✍ Ganja, Edward A.; Ontiveros, Cynthia D.; Morrison, John A. 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 567 KB

Silver Compounds in Synthetic Chemistry.

Silver Compounds in Synthetic Chemistry. 1 A Facile Preparative Route for Pentafluorophenylsilver, AgC6F5 and its Use as an Oxidative Pentafluorophenyl Group Transfer Reagent in Reactions with Group 12 to 16 Elements — the Single Crystal Structure of AgC6F5 · EtCN, the First Arylsilver Derivative Crystallising in Infinite Chains

✍ Wieland Tyrra; Mathias S. Wickleder 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 2 views

AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c