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Mild methods for the in situ generation of trimethylsilyl iodide

โœ Scribed by Michael E. Jung; Todd A. Blumenkopf

Book ID
104246046
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
230 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

We have shown that trimethylsilyl iodide I_ is a very useful reagent for a number of important organic transformations including: the dealkylative hydrolysis of ethers,' esters, 3 carbamates, 4

๐Ÿ“œ SIMILAR VOLUMES

A new mild procedure for the direct coup
A new mild procedure for the direct coupling of 1-trimethylsilyl acetylenes with vinyl triflates or aryl iodide
โœ Ulla Halbes; Patrick Pale ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 61 KB

1-Trimethylsilyl acetylenes can be directly coupled with vinyl triflates or aryl iodide in the presence of the appropriate amount of potassium carbonate and methanol and a catalytic amount of AgCl and Pd(PPh 3 ) 4 . Functionalized enynes can thus be obtained in good to excellent yields without prior