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Mild and regioselective iodination of electron-rich aromatics with N-iodosuccinimide and catalytic trifluoroacetic acid

✍ Scribed by Anne-Sophie Castanet; Françoise Colobert; Pierre-Emmanuel Broutin

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
171 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

A variety of aromatics compounds substituted with methoxy or methyl groups were regioselectively iodinated with N-iodosuccinimide and catalytic trifluoroacetic acid with excellent yields under mild conditions and short reaction times.

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An efficient and regioselective method for iodination of electron-rich aromatic compounds was found using N-chlorosuccinimide and sodium iodide in AcOH with short reaction times. This method is also applicable to non-benzenoid aromatic or heteroaromatic compounds.

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