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Mild alkoxycarbonylation of olefins in the presence of palladium complexes

✍ Scribed by E. G. Chepaikin; A. P. Bezruchenko; A. Benjeu; A. Joo


Book ID
112447571
Publisher
Springer
Year
1989
Tongue
English
Weight
69 KB
Volume
38
Category
Article
ISSN
1573-9171

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In the presence of methanesulfonic acid, the palladium(0)-olefin complexes: [Pd( 2 -ol)(P-N)] [ol = dimethyl fumarate or fumaronitrile, P-N = 1-(Ph 2 P)C 6 H 4 -2-CH=NR (R = CMe 3 or C 6 H 4 OMe-4)] catalyse the alkoxycarbonylation of terminal alkynes. Moderately good rates are obtained when the cat