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Highly efficient Heck olefin arylation in the presence of iminophosphine–palladium(0) complexes

✍ Scribed by Alberto Scrivanti; Matteo Bertoldini; Ugo Matteoli; Valentina Beghetto; Simonetta Antonaroli; Alessia Marini; Bruno Crociani


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
81 KB
Volume
235
Category
Article
ISSN
1381-1169

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In the presence of methanesulfonic acid, the palladium(0)-olefin complexes: [Pd( 2 -ol)(P-N)] [ol = dimethyl fumarate or fumaronitrile, P-N = 1-(Ph 2 P)C 6 H 4 -2-CH=NR (R = CMe 3 or C 6 H 4 OMe-4)] catalyse the alkoxycarbonylation of terminal alkynes. Moderately good rates are obtained when the cat

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