𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Migration aptitudes in the photolysis of some tertiary alkyl azides

✍ Scribed by Montgomery, Frederick C.; Saunders, William H.

Book ID
127186193
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
692 KB
Volume
41
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Dimethylsulphide as a nitrene trap in th
Dimethylsulphide as a nitrene trap in the photolysis of some phosphinic azides
✍ Martin J.P. Harger; Sally Westlake πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 132 KB

When PhRP(0)N3 (R = Ph or t-Du) is photolysed in dimethylsulphide substantial amounts (22 -3276) of PhRP(O)N:SMeZand PhRP(0)NHCH2SMe are produced and rearrangement is less important than in benzene. Phosphinic azides eliminate N2 on photol.ysis. The major pathway in methanol involves rearrangement t

Structural effects of the Grunwald–Winst
Structural effects of the Grunwald–Winstein correlations in the solvolysis of some simple tertiary alkyl chlorides
✍ Kenichi Takeuchi; Yasushi Ohga; Takushiro Ushino; Masaaki Takasuka πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 104 KB πŸ‘ 2 views

The rates of solvolysis in various solvents at 25 Β°C were determined for five tertiary alkyl chlorides: 2-chloro-2,4,4-trimethylpentane ( 4), 2-chloro-2,4-dimethylpentane, 2-chloro-2-methylpentane, 1-chloro-1,3,3-trimethylcyclopentane (7) and 1-chloro-1-methylcyclopentane. The rate data were analyse