Structural and Solvent Effects in the Solvolysis of Some Tertiary Alkyl Chlorides. Limiting Solvolysis and Classical Mechanisms. Fact or Fiction? An Answer in the Light of the Unified Theory

Structural effects of the Grunwald–Winst

Structural effects of the Grunwald–Winstein correlations in the solvolysis of some simple tertiary alkyl chlorides

✍ Kenichi Takeuchi; Yasushi Ohga; Takushiro Ushino; Masaaki Takasuka 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 104 KB

The rates of solvolysis in various solvents at 25 °C were determined for five tertiary alkyl chlorides: 2-chloro-2,4,4-trimethylpentane ( 4), 2-chloro-2,4-dimethylpentane, 2-chloro-2-methylpentane, 1-chloro-1,3,3-trimethylcyclopentane (7) and 1-chloro-1-methylcyclopentane. The rate data were analyse