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Mid-Infrared Spectrum of [Ru(bpy) 3 ] 2+ *

โœ Scribed by Omberg, Kristin M.; Schoonover, Jon R.; Treadway, Joseph A.; Leasure, Robert M.; Dyer, R. Brian; Meyer, Thomas J.


Book ID
127294796
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
215 KB
Volume
119
Category
Article
ISSN
0002-7863

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The optical absorption spectrum of excited ruthenium tri.-bipyridyi (Ru(bpy)s++) in the range of 244-500 nm is determined by applying the method of intensity dependence measurement.

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ESR of [Fe(bpy)3l+and [ Ru(bpy)3]+suggests that the reduction electron IS located on a smgle hgand rather than delomhzed over dl three In solohon the electron hops from one Irgand to another. broadenmg the ESR hne In the trtply reduced jFe(bpy)s j-and 1 Ru(bpy), )-. one electron IS on each Itgsnd a