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Microwave spectrum, quadrupole coupling constants, and dipole moment of nitroethylene

✍ Scribed by H.D. Hess; A. Bauder; Hs.H. Günthard


Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
802 KB
Volume
22
Category
Article
ISSN
0022-2852

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The rotational spectrum of oxiranecarbonitrile has been measured between 8 and 40 GHz with a Stark spectrometer and a waveguide Fourier transform microwave spectrometer. Three rotational constants, five centrifugal distortion constants, and the diagonal elements of the 14 N quadrupole coupling tenso

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✍ G.L. Blackman; R.D. Brown; F.R. Burden; J.E. Kent 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 228 KB

The microwave spectra of the 803e and 789e isotopic species of 1,2,5-selenadiazole have been assigned and analyzed. The inertial defect shows the molecule to be planar compatable with Czv symmetry. The dipole moment is 1.11 f 0.03 D. 5.2 \* 0.3 MHz. 14N quadrupole coupling constants are ]w] < 1 MHz