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Microwave spectrum of N2D4, 14N quadrupole coupling constants, and the barrier to inversion of the amino group

โœ Scribed by Marlin D. Harmony; Paul A. Baron

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
549 KB
Volume
38
Category
Article
ISSN
0022-2860

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The microwave spectrum, structure, dipol
The microwave spectrum, structure, dipole moment, and 14N nuclear quadrupole coupling constant of acetonitrile-N-oxide
โœ P.B. Blackburn; R.D. Brown; F.R. Burden; J.G. Crofts; I.R. Gillard ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 244 KB

The microwave spectrum of acetonitrile N-oxide shows that the molecule is a symmetric top. The spectrum of the common isotopic species, both 1% species. the 15N and 180 species have been assigned leading to the r, geometry of all heavy atoms. The nitrogen quadrupofe coupling cehstant is found to be