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Microwave spectra, hyperfine splittings and average structures of 3,3,3-trifluoropropyne, CF3C?CH and trifluoroacetonitrile, CF3CN

โœ Scribed by Cox, A. Peter; Ellis, Mark C.; Legon, A. C.; Wallwork, Andrew


Book ID
121358235
Publisher
Royal Society of Chemistry
Year
1993
Tongue
English
Weight
832 KB
Volume
89
Category
Article
ISSN
0956-5000

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The reactions of Zn(CF 3 )Br ยด2 CH 3 CN, Cd(CF 3 ) 2 ยด2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br ยด2 CH 3 CN yields (Ndifluoromethyl)-4-N,N