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Microwave-optical double resonance of the triplet state of cyclopentanone

✍ Scribed by Albert L. Shain; Wei-Tau Chiang; Mark Sharnoff

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
429 KB
Volume
16
Category
Article
ISSN
0009-2614

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✦ Synopsis

Fine structure and hyperfine structure information on the chemically reactive 3n~t state of cyclopentanone is obtained by the low field microwave-optical double resonance (MODOR) technique. The hvperfine structure is interpreted ter.tatively to indicate rtit the nxsnetic z asis lies perpendicular to the cxbonyl bond and nearly parallel to the Cs-CL--C2 plane. 'IlIe principal values of the fine structure spin hamiltonian arc D/hc=~0.1404~0.0001

cm-', Ehc = T 0.027! + 0.000 1 cm-'.

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