Microwave-expedited olefin epoxidation over hydrotalcites using hydrogen peroxide and acetonitrile
โ Scribed by Unnikrishnan R Pillai; Endalkachew Sahle-Demessie; Rajender S Varma
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 92 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
An efficient microwave-assisted epoxidation of olefins is described over hydrotalcite catalysts in the presence of hydrogen peroxide and acetonitrile. This general and selective protocol is extremely fast and is applicable to a wide variety of substrates. Published by Elsevier Science Ltd. Scheme 1.
๐ SIMILAR VOLUMES
Hydrotalcite-Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide and Amide Compounds. -A triphasic oxidation system, consisting of aqueous H 2 O 2 , amide, solid hydrotalcite as base catalyst, and anionic surfactant in dichloroethane, is examined on various olefins. Isobutyramide is found to b