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Microwave-expedited olefin epoxidation over hydrotalcites using hydrogen peroxide and acetonitrile

โœ Scribed by Unnikrishnan R Pillai; Endalkachew Sahle-Demessie; Rajender S Varma


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
92 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


An efficient microwave-assisted epoxidation of olefins is described over hydrotalcite catalysts in the presence of hydrogen peroxide and acetonitrile. This general and selective protocol is extremely fast and is applicable to a wide variety of substrates. Published by Elsevier Science Ltd. Scheme 1.


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Hydrotalcite-Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide and Amide Compounds. -A triphasic oxidation system, consisting of aqueous H 2 O 2 , amide, solid hydrotalcite as base catalyst, and anionic surfactant in dichloroethane, is examined on various olefins. Isobutyramide is found to b