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Microwave-assisted Oxidation of Alcohols and Polyarenes with Cetyltrimethylammonium Bromochromate

โœ Scribed by Mohammad Kazem MOHAMMADI; Shahriare GHAMMAMY; Hossein IMANIEH

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
70 KB
Volume
27
Category
Article
ISSN
0256-7660

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โœฆ Synopsis

Abstract

An efficient and mild methodology for oxidation of alcohols and polyarenes was described using cetyltrimethylammonium bromochromate (CTMABC) under microwave irradiation. Primary and secondary alcohols and polyarenes could be selectively oxidized under microwave irradiation into the corresponding aldehydes and ketones in high yields and short reaction time, using commercially available and magnetically retrievable oxidative material (CTMABC).

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โœ Laura Palombi; Francesco Bonadies; Arrigo Scettri ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 413 KB

Under microwave irradiation 3A molecular sieves promote the oxidation of secondary (linear and cyclic) and benzylic alcohols to the corresponding carbonyl compounds by t-butyl hydroperoxide. Under the same conditions, ct,13-unsaturated alcohols are converted into Qt,13-epoxyalcohols in regio-and dia