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Microwave-Assisted Deprotection of N,N-Dimethylhydrazones in Water Using Palladium Chloride—Tin Chloride as Catalyst.

✍ Scribed by Rahman Hosseinzadeh; Ali Sharifi; Kourosh Tabar-Heydar; Farshid Mohsenzadeh


Publisher
John Wiley and Sons
Year
2003
Weight
86 KB
Volume
34
Category
Article
ISSN
0931-7597

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A CNDO insight to the alcoholysis of N-s
✍ W.K. Glass; I.J. King; A. Shiels 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 192 KB

Using the CNDO/2 method, the electron densities in p-NOz, p-Cl, and p-H N-Sulphinylanilines were computed. The electron densities at sulphur were found to be proportional to the Hammett a-values of the substituents and also to log k, for the alcoholysis. The activation energy, Arrhenius factor and A