✦ LIBER ✦

Microstructure, Kinetics, and Transport in Oil-in-Water Microemulsion Polymerizations

✍ Scribed by Jennifer O'Donnell; Eric W. Kaler

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 259 KB
Volume: 28
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200700055

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The kinetics of microemulsion polymerization depend on the structure of the initial microemulsion and the transport of species between the aqueous domain, the micelles, and the polymer particles. The water solubility of the monomer and the proximity of the initial microemulsion composition to a phase boundary are key considerations for studying microemulsion polymerization kinetics and producing the desired products. Complications frequently arise in the synthesis of copolymers or the incorporation of controlled polymerization mechanisms because of the compartmentalized nature of microemulsion polymerizations.

magnified image

📜 SIMILAR VOLUMES

Microstructure and Diffusion Properties

Microstructure and Diffusion Properties of Oil-in-Water Vinyltoluene Microemulsions

✍ J. SANTHANALAKSHMI; K. ANANDHI 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 117 KB

Kinetic Model for Reactivity in Quaterna

Kinetic Model for Reactivity in Quaternary Water-in-Oil Microemulsions

✍ Luis García-Río; Pablo Hervella 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 1 views

Kinetic studies of Chromobacterium visco

Kinetic studies of Chromobacterium viscosum lipase in AOT water in oil microemulsions and gelatin microemulsion-based organogels

✍ Tuah R.-J. Jenta; Greg Batts; Gareth D. Rees; Brian H. Robinson 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB 👁 2 views

Kinetic studies have shown that octyl decanoate mulsion are to a large extent preserved on transformation synthesis by Chromobacterium viscosum (CV) lipase in to the daughter organogel. The close agreement of apparsodium bis-2-(ethylhexyl) sulfosuccinate (AOT) water in ent activation energies sugges

Kinetics of the Formation of Nano-Sized

Kinetics of the Formation of Nano-Sized Platinum Particles in Water-in-Oil Microemulsions

✍ Hanna Härelind Ingelsten; Rahul Bagwe; Anders Palmqvist; Magnus Skoglundh; Chris 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 106 KB

The effect of surfactant type and temperature on the kinetics of the formation of platinum nanoparticles in water-in-oil microemulsions by chemical reduction of PtCl 2- 6 were examined with timeresolved UV-vis absorption spectroscopy. The surfactants used were poly(ethylene glycol)monododecyl ethers

Photoinitiated copolymerization of acryl

Photoinitiated copolymerization of acrylamide and styrene in oil-in-water microemulsion

✍ Liping Zhang; Zhaohua Zeng; Yonglie Chen; Chi Wu; Jun Gao 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB 👁 2 views

This article describes the copolymerization of acrylamide with styrene in oil-in-water microemulsion, using dodecyl betaine as emulsifier and a-hydroxy-a,adimethyl acetophenone or a,a-dimethoxy-phenyl acetophenone as photoinitiator. Results indicated that the photoinitiation of polymerization occurs

Kinetics of Proton Transport in Water

✍ A. A. Kornyshev; A. M. Kuznetsov; E. Spohr; J. Ulstrup 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 55 KB