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Microstructure and mechanical and thermal properties of ternary carbides in Hf–Al–C system

✍ Scribed by L.F. He; Y.W. Bao; J.Y. Wang; M.S. Li; Y.C. Zhou


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
793 KB
Volume
57
Category
Article
ISSN
1359-6454

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✦ Synopsis


A Hf-Al-C composite composed of Hf 3 Al 3 C 5 , Hf 2 Al 4 C 5 and Hf 3 Al 4 C 6 has been successfully synthesized by a hot pressing method; its microstructure and mechanical and thermal properties were systematically characterized. Hf-Al-C composite conserves the high hardness and stiffness similar to HfC. Interestingly, the composite exhibits much higher strength and fracture toughness than HfC due to its fine and anisotropic grains. Diffusion-accommodated grain-boundary sliding of Hf-Al-C ceramics at high temperature is inhibited by glass-free grain boundaries and tight interlocking of grains at grain-edge triple junctions, resulting in high remaining stiffness up to 1600 °C. Dislocations on the basal planes of Hf-Al-C ceramics with a Burgers vector of 1 3 h1 1 2 0i can be activated at high temperature. Hf-Al-C composite shows higher coefficient of thermal expansion and specific heat capacity as well as lower thermal conductivity than HfC. The superior mechanical and thermal properties make Hf-Al-C compounds good high-temperature structural materials.


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