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Microstructure analysis of ethylene/1-hexene co-polymers with embeddedrac-Et[Ind]2ZrCl2metallocene catalyst

✍ Scribed by Dong Min Shin; Viet Hung Pham; Kyoung Won La; In Kyu Song; Jin Suk Chung


Book ID
105700673
Publisher
Springer Netherlands
Year
2008
Tongue
English
Weight
196 KB
Volume
34
Category
Article
ISSN
0922-6168

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Copolymerization of ethylene and 1-hexene was carried out with different catalysts (homogeneous Et [Ind] 2 ZrCl 2 , supported Et[Ind] 2 ZrCl 2 and in-situ supported Et[Ind] 2 ZrCl 2 ). The novel in-situ supported metallocene catalyst showed higher activity than the corresponding supported metallocen

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A silica-magnesium bisupport (SMB) was prepared by a sol-gel method for use as a support for a metallocene/Ziegler-Natta hybrid catalyst. The SMB was treated with methylaluminoxane (MAO) prior to the immobilization of TiCl 4 and rac-Et(Ind) 2 ZrCl 2 . The prepared rac-Et(Ind) 2 ZrCl 2 /TiCl 4 /MAO/S