The copolymerization of ethylene and 1-octadecene using a bridged metallocene was studied in order to observe the effect of the comonomer on the catalytic activity. A noticeable increase in activity is seen as the concentration of 1-octadecene in the reaction medium increases. 13 C NMR analysis show
✦ LIBER ✦
Synthesis of ethylene-α-olefin alternating copolymers with Et(1-Ind)(9-Flu)ZrCl2-MAO catalyst system
✍ Scribed by Toshiya Uozumi; Cheol-Hee Ahn; Mikio Tomisaka; Jizhu Jin; Gonglu Tian; Tsuneji Sano; Kazuo Soga
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 59 KB
- Volume
- 201
- Category
- Article
- ISSN
- 1022-1352
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A mathematical model for the homogeneous terpolymerization of ethylenepropylene-diene (EPDM) in a semibatch reactor using Et(Ind) 2 ZrCl 2 /MAO as a catalyst system was developed and reported herein. In this study, we developed a kinetic model in order to explain the catalyst and EPDM properties suc