A review of the recent work on acceleration of graphitization under high pressure
Microscopic observation of graphitization under high pressure
โ Scribed by T. Noda; M. Inagaki; K. Kamiya
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 112 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0008-6223
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โฆ Synopsis
Structural changes which accompany the catalytic graphitization of carbon have been investigated. Utilizing X-ray diffraction and high temperature microscopy techniques, the effectiveness of various additives in promoting the formation of graphite from a variety of carbon materials of varying degrees of graphitizability is elucidated.
- The development of mesophase microstructures during pyrolysis of selected coker feedstocks R. J. Price and J. L. White (Gulf General Atomic Company, Sand Diego, California). Polarized light microscopy was used to observe the formation of mesophase microstructures during the pyrolysis of selected coker feedstocks, including a vacuum-reduced crude, an air-blown asphalt, a thermal tar, and gilsonite. These materials developed a range of microstructural components characterized by extinction contour patterns differing widely in anisotropy and contour spacing.
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The two hard carbons PH-7, a phenolformaldehyde resin char carbonized to 700ยฐC and PH-15, which was the same PH-7 heat-treated for 60min at 1500ยฐC under reduced pressure, were heat-treated at various temperatures under pressure of 5 kbar and examined using a polarized light microscope. Bright golden
Non-graphitizing carbon beads were heat-treated to 1300" -1900" under 5 kbar. Whereas the original beads carbonized at looo" graphitize abruptly at 1500" -16CV, the pre-heated ones demand higher temperature for their graphitization. The 1500"-pre-heated and 2100"-pre-heated graphitized above 17M1",
## ABSTRACTS that the shape and sharpness of the three-dimensional ( 101) and ( 112) reflection, respectively, are considerably developed with time, whereas the mean interlayer spacing as determined by the (004) line is not changed significantly for holding times longer than 15 min.