For the study of the microporous structure of coal, semicoke and cokes the carbon dioxide isotherms within the temperature range from 195 to 298 K have been applied. The determination of pore-size distribution and effective surface area of micropores .Smkro was carried out by means of relations deri
Micropore structure analysis of coal from adsorption isotherms of methanol
✍ Scribed by Zdenĕk Spitzer; Václav Bíba; Frantis̆ek Bohác̆; Eva Málková
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 614 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0016-2361
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✦ Synopsis
Results are presented of a study of the distribution of pore volume and surface in micropores of coal from adsorption equilibria of methanol vapours at temperatures ranging between 293 and 343 K according to a new method. Typical parameters of the micropore: structure of twenty samples of coals of carbon contents between 64 and 91% are calculated for a model of cylindrical pores. The micropore surface areas are compared with the results obtained by using the DKR and BET equations, and with already published kata from small-angle X-ray scattering. The agreement between results is satisfactory, This evidence suggests that the use of the new method of evaluating the basic parameters of the microstructure can be recommended.
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SY N
Three crystalline substances were isolated from the methanol-soluble portion (SBM) of the extracted residues from pyridine extracts of Sorachi coal with hexane. They were characterized by using the i.r., u.v., 'H n.m.r. and mass spectra together with the ultimate analysis. Two cannot be clearly defi