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Microemulsion copolymerization of vinyl acetate and butyl acrylate using a mixture of anionic and non-ionic surfactants

✍ Scribed by Víctor M. Ovando-Medina; René D. Peralta; Eduardo Mendizábal; Hugo Martínez-Gutiérrez; Miguel A. Corona-Rivera

Publisher
Springer
Year
2010
Tongue
English
Weight
327 KB
Volume
66
Category
Article
ISSN
0170-0839

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Reactivity ratios and monomer partitioni
Reactivity ratios and monomer partitioning in the microemulsion copolymerization of vinyl acetate and butyl acrylate
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## Abstract The true monomer reactivity ratios for the vinyl acetate/butyl acrylate system were determined with experimental data from the cumulative copolymer composition at low, intermediate, and high conversions and with the monomer partitioning among the aqueous, microemulsion droplet, and poly

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## Abstract The copolymerization kinetics of conventional emulsions and miniemulsions of 50:50 and 25:75 molar ratios vinyl acetate–butyl acrylate monomer mixtures were studied using sodium hexadecyl sulfate as surfactant. Hexadecane was the cosurfactant used in the preparation of the miniemulsions