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Microdynamic motion of tetrahedral clusters studied by 59Co and 99Ru NMR relaxations

✍ Scribed by GRANGER, P.; RICHERT, T.; ELBAYED, K.; KEMPGENS, P.; HIRSCHINGER, J.; RAYA, J.


Book ID
120460804
Publisher
Taylor and Francis Group
Year
1997
Tongue
English
Weight
226 KB
Volume
92
Category
Article
ISSN
0026-8976

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## Abstract A series of mixed‐metal carbonyl clusters containing Co and Ru atoms was investigated by ^59^Co NMR and, for the first time in cluster chemistry, by ^99^Ru NMR. These techniques were successfully used to follow the reactivity of these complexes towards nitrosylation by NO^+^. Whereas [N

The chemistry of heteronuclear clusters