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59Co-NMR spectroscopy of the tetrahedral cluster Co4(CO)12: relaxation and exchange

✍ Scribed by Christina Sizun; Pierre Kempgens; Jésus Raya; Karim Elbayed; Pierre Granger; Jacky Rosé


Book ID
108346645
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
137 KB
Volume
604
Category
Article
ISSN
0022-328X

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Spin-7/2 central line intensities are calculated for any ratio of the quadmpolar coupling constant to the radiofrequency field for both one-pulse and two-pulse Hahn-echo experiments and tested by 59Co NMR on the model compounds, Na,[Co(NO,),] and trans-[Co(en),(N0,)2]N03. The Hah -h n ec o se q uen