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Microbiological enantioselective reduction of ethyl acetoacetate

✍ Scribed by Joyce Benzaquem Ribeiro; Maria da Conceição Klaus V Ramos; F.R.de Aquino Neto; Selma Gomes Ferreira Leite; O.A.C Antunes

Book ID
114396010
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
61 KB
Volume
24-25
Category
Article
ISSN
1381-1177

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✍ Martin Bertau 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 59 KB

In the course of investigating microbial syntheses for chiral pharmaceutical intermediates, ethyl 4,4,4-trifluoro acetoacetate (1) was submitted to baker's yeast reduction. With the purpose of obtaining the D-carbinol in high enantiopurity, several additives were tested for L-reductase inhibitor act