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Microbial degradation of the phytosterol side chain. II. Incorporation of [14C]-NaHCO3 onto the C-28 position

โœ Scribed by Fujimoto, Yoshinori; Chen, Ching Shih; Gopalan, Aravamudan S.; Sih, Charles J.


Book ID
126899809
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
298 KB
Volume
104
Category
Article
ISSN
0002-7863

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## Abstract Irradiation of Nโ€stearoylimidazole (**1**) gave hexadecโ€1โ€ene (**4**) in 45% yield, whereas irradiation of Nโ€(4โ€methylstearoyl)imidazole (**13**) possessing a tertiary hydrogen atom ฮณ to the carbonyl group led to 2โ€methylhexadecโ€1โ€ene (**14**) in 62% yield. These results are explained b