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Determination of the Stereochemistry of C-2’ and C-3’ Positions of Taxine NA-1 (2’-Hydroxytaxine II) by the Asymmetric Synthesis of the Reductive Degradation Product of Its Side Chain Moiety

✍ Scribed by Tang, Wanxia; Ando, Masayoshi; Minato, Hiroshi; Ando, Mariko


Book ID
118252029
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2012
Tongue
English
Weight
869 KB
Volume
85
Category
Article
ISSN
0385-5414

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Photochemische Reaktionen. 92. Mitteilun
✍ Shigeo Iwasaki 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 728 KB

## Abstract Irradiation of N‐stearoylimidazole (**1**) gave hexadec‐1‐ene (**4**) in 45% yield, whereas irradiation of N‐(4‐methylstearoyl)imidazole (**13**) possessing a tertiary hydrogen atom γ to the carbonyl group led to 2‐methylhexadec‐1‐ene (**14**) in 62% yield. These results are explained b