Micellar nickel(II)-2-pyridineketoxime complexes as powerful catalysts of the cleavage of carboxylic acid esters in weakly acidic conditions

✍ Scribed by Jan Budka; Frantisek Hampl; Frantisek Liska; Paolo Scrimin; Paolo Tecilla; Umberto Tonellato

• Book ID: 103997602
• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 369 KB
• Volume: 104
• Category: Article
• ISSN: 1381-1169
• DOI: 10.1016/1381-1169(95)00258-8

✦ Synopsis

Metallomicelles made of Ni( II) complexes of lipophilic 2-pyridineketoximes such as 2 or 3a and CTABr, in water at pH 4, accelerate the cleavage of p-nitrophenyl hexanoate over a half million fold.