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Metallomicelles Made of Ni(II) and Zn(II) Complexes of 2-Pyridinealdoxime-Based Ligands as Catalyst of the Cleavage of Carboxylic Acid Esters †

✍ Scribed by Mancin, Fabrizio; Tecilla, Paolo; Tonellato, Umberto

Book ID
120199165
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
135 KB
Volume
16
Category
Article
ISSN
0743-7463

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Micellar nickel(II)-2-pyridineketoxime c
Micellar nickel(II)-2-pyridineketoxime complexes as powerful catalysts of the cleavage of carboxylic acid esters in weakly acidic conditions
✍ Jan Budka; Frantisek Hampl; Frantisek Liska; Paolo Scrimin; Paolo Tecilla; Umber 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 369 KB

Metallomicelles made of Ni( II) complexes of lipophilic 2-pyridineketoximes such as 2 or 3a and CTABr, in water at pH 4, accelerate the cleavage of p-nitrophenyl hexanoate over a half million fold.