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Methyltrioxorhenium as Catalyst for Olefin Metathesis

✍ Scribed by Prof. Dr. Wolfgang A. Herrmann; Dr. Werner Wagner; Uwe N. Flessner; Ursula Volkhardt; Dr. Hartmut Komber


Book ID
102726546
Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
511 KB
Volume
30
Category
Article
ISSN
0044-8249

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Methyltrioxorhenium as Catalyst for Olef
✍ Prof. Dr. Wolfgang A. Herrmann; Richard W Fischer; Dr. Dieter W. Marz πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 473 KB πŸ‘ 1 views

The pronounced Lewis acidity explains the exceptional activity of the title compound as catalyst for olefin epoxidations with hydrogen peroxide. The system MTO/__t__BuOH/H~2~O~2~ transforms olefins selectively and efficiently into epoxides under very mild conditions (βˆ’30 to + 60Β°C, but normally at r