Methyltrioxorhenium as Catalyst for Olef
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Prof. Dr. Wolfgang A. Herrmann; Richard W Fischer; Dr. Dieter W. Marz
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Article
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1991
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John Wiley and Sons
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English
β 473 KB
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The pronounced Lewis acidity explains the exceptional activity of the title compound as catalyst for olefin epoxidations with hydrogen peroxide. The system MTO/__t__BuOH/H~2~O~2~ transforms olefins selectively and efficiently into epoxides under very mild conditions (β30 to + 60Β°C, but normally at r