Methyl N-(Benzylsulfonyl)oxamate as a Probable Intermediate in the Synthesis of 4-Hydroxy-5-phenyl-3(2H)-isothiazolone 1,1-Dioxide from Phenylmethanesulfamide and Dimethyl Oxalate in the Presence of Bases. -The base-mediated formation of the title isothiazolone dioxide (III) from phenylmethanesulfa
✦ LIBER ✦
MethylN-(benzylsulfonyl)oxamate as a probable intermediate in the synthesis of 4-hydroxy-5-phenyl-3(2H)-isothiazolone 1,1-dioxide from phenylmethanesulfamide and dimethyl oxalate in the presence of bases
✍ Scribed by S. G. Zlotin; A. I. Gerasyuto
- Book ID
- 105595230
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 158 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1573-9171
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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## Abstract Reactions of ethyl 3‐[(__E__)‐(dimethylamino)methylidene]pyruvate (**3**) and 3‐[(dimethylamino)methyl‐idene]‐2‐oxosuccinate (**4**) with hydrazine monohydrochloride (**5a**) and (hetero)arylhydrazines (**5b‐i**) afforded, regioselectively, 1‐substituted ethyl 1__H__‐pyrazole‐5‐carboxyl