Methylene-Bridged Dinuclear Gold(III) Complexes with Terminal and Bridging Ylide Ligands
โ Scribed by Prof. Dr. Hubert Schmidbaur; Dipl.-Chem. Christoph Hartmann
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 337 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Base hydrolysis reactions of [Cr(tmpa)(NCSe)] 2 O 2ฯฉ , [Cr(tmpa)(N 3 )] 2 O 2ฯฉ , and follow the pseudo-first-4ฯฉ 2ฯฉ [Cr (tmpa) (ฯชO)(ฯชPhPO )] [ Cr (tmpa) (ฯชO)(ฯชCO )] 2 2 4 2 2 3 order relationship (excess OH ฯช ): For the com- obsd o b p p 3 plex, ฯช2 ฯช1 k (60ะC) ฯญ (1.50 ฯฎ 0.03) ฯซ 10 s ; โฌH โก ฯญ 61 ฯฎ
Addition of p-tert-butylcalix[4]arene LH 4 to the dinuclear ported by two bridging ยต 2 -ฮบ 2 O,ฮบ 2 O-calix[4]arene ligands in compounds M 2 (NMe 2 ) 6 (M = Mo, W) results in the formation the solid state. These compounds are the first examples of a of [NH 2 Me 2 ] 2 [L 2 M 2 ] 1 (M = Mo) and 2 (M = W
## Abstract Two linear, trinuclear mixedโvalence complexes, [Co^II^{(ฮผโL^1^)(ฮผโOAc)Co^III^(OAc)}~2~] (1) and [Co^II^{(ฮผโL^2^)(ฮผโOAc)Co^III^(OAc)}~2~] (2) and two mononuclear Co^III^ complexes [Co^III^{L^3^}(OAc)] (3), and [Co^III^{L^4^}(OAc)] (4) were prepared and the molecular structures of 1, 2 a