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Breaking the Rule: Synthesis and Molecular Structure of Dinuclear Rhodium Complexes with Bridging and Semibridging Trialkylphosphane Ligands

✍ Scribed by Thomas Pechmann; Carsten D. Brandt; Helmut Werner


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
111 KB
Volume
39
Category
Article
ISSN
0044-8249

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The Bridging Function of an Apparently N
✍ Peter Schwab; Justin Wolf; Norbert Mahr; Paul Steinert; Ulrich Herber; Helmut We 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 2 views

Novel dinuclear rhodium complexes of the general composition [Rh2Cl2(mu-CRR')2(mu-SbiPr3)] (4-6) were prepared by thermolysis of the mononuclear precursors trans-[RhCl(=CRR')(SbiPr3)2] in excellent yield. The X-ray crystal structure analysis of 4 (R = R' = Ph) confirms the symmetrical bridging posit