Synthesis of 1,6-anhydro-2,3-di-O-benzoy
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Yoshitaka Ichikawa; Hiroyoshi Kuzuhara
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Article
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1983
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Elsevier Science
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English
⚖ 986 KB
The title compound (21) was synthesized from cellobiose as a synthon of a heparin-related oligosaccharide. The per-0-benzyl and per-0-benzoyl derivatives of 1 ,6-anhydro-4-0-(6-deoxy-B-D-~~~lo-hex-5-enopyranosyl)-~-~-glucopyranose were treated with a nonsolvated borane to give a 1 :2 mixture of the