๐”– Bobbio Scriptorium
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Methylation of carbohydrates with lithium methylsulphinyl carbanion

โœ Scribed by Anthony B. Blakeney; Bruce A. Stone


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
468 KB
Volume
140
Category
Article
ISSN
0008-6215

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Reactions of the carbanion of chlorometh
โœ Mieczysล‚aw Mฤ…kosza; Natalia Urbaล„ska; Alexey A. Chesnokov ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 159 KB

Addition of the carbanion of chloromethyl methyl sulfone to aldehydes and ketones proceeds faster than its degradation via the Ramberg-Baecklund reaction. Chlorohydrins and oxiranes produced from aldehydes treated with an excess of base undergo the Ramberg-Baecklund reaction giving allylic alcohols,