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Methylation of 2,4-dihydro-3H-1,2,4-triazol-3-ones. A structural determination of anhydro-5-aryl-1,4-dimethyl-3-hydroxy-1,2,4-triazolium hydroxides by two dimensional NMR

โœ Scribed by Edward W. Huber; John M. Kane


Book ID
112129820
Publisher
Journal of Heterocyclic Chemistry
Year
1990
Tongue
English
Weight
254 KB
Volume
27
Category
Article
ISSN
0022-152X

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The Schiff bases 3a-h obtained from 4-amino-1,2,4-triazol-3-ones 1a-h when subjected to Japp-Klingemann reaction yielded the corresponding 3-{2-[(2-aryl-5-methyl-3H-[1,2,4]-triazol-3-one-4-yl)]-iminophenyl}-pentane-2,4-diones 4 a-h. These diones on cyclisation with N 2 H 4 yielded the title compound