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Chemical Reactivity of 3-Aryl-5-methyl-1,3,4-oxadiazolin-2-ones Towards Nitrogen Nucleophiles. Part 1. One-Pot Ring Conversion of 3-Aryl-5-methyl-1,3,4-oxadiazolin-2-ones into 4-Amino-2-aryl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-ones.

✍ Scribed by Jyothi R. Kavali; O. Kotresh; Bharati V. Badami


Publisher
John Wiley and Sons
Year
2004
Weight
82 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Aziridinone / u-Lactam 1 Decarbonylation Photolysis of 3-Methyl-5.5-dipheny1-3,5-dihydro-4H-1,2,3-tria~ol-4-0ne~'~ Irradiation (h 2 280 nm) of a degassed solution in deuterated benzene of the dihydro-1,2,3-triazolone 5 yields the dihydroin-dolone 7, the imine 9, and its photoreduction product 10, be