The protonation constants and the complex stability constants of 1,7-dioxa-4,10,13triazacyclopentadecane-4,10,13-tripropionic acid (N-pr 3 [15]ane N 3 O 2 ) with some first-row transition metals (Co 2+ , Ni 2+ , Cu 2+ , and Zn 2+ ) and lanthanide metals (Ce 3+ , Eu 3+ , Gd 3+ , and Yb 3+ ) have been
Methyl methylphenylphosphinate, MePh(MeO)PO complexes of the first row transition metals
β Scribed by Chester M. Mikulski; Joseph Unruh; Louis L. Pytlewski; Nicholas M. Karayannis
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 566 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The enthalpy change of the complexation reactions of the firstβrow transitional metal chlorides including CrCl~3~, MnCl~2~, FeCl~2~, CoCl~2~, NiCl~2~ and CuCl~2~ with LβΞ±βhistidine in water were determined by a microcalorimeter at 298.15β323.15 K. The standard enthalpy of formation of C
Density functional theory/Hartree-Fock hybrid methods have been applied to the cationic methylene complexes MCH~of the first-row transition metals (M = Sc-Cu). A comparison of the computed results with earlier high-level ab initio MO calculations and experimental data is presented in order to assess