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Methyl 9,14-didehydro-4,5-epoxy-3-methoxy-17-methyl-.alpha.-methylene-6-oxothebinan-8.beta.-acetate

✍ Scribed by Singh, Amrik; Kullnig, Rudolph K.; Seyed-Mozaffari, Ahmad; Archer, Sydney

Book ID
127066383
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
401 KB
Volume
51
Category
Article
ISSN
0022-3263

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## 9. VIII.93) Nucleophilic substitution of 6p-chloro-7,8-didehydro-4,5~ -epoxy-3-methoxy-17-rnethylmorphinan (1) and 8a -brom0-6,7-didehydro-4,5~ -epoxy-3-methoxy-17-methylmorphinan (2) with lithium cyano(methy1)-and (aryl)cyanocuprates(I) (5a-c) was accompanied by allylic rearrangement with both