Methyl 4-(4-chlorophenyl)-1-methylpiperidine-4-carboxylate
✍ Scribed by Zhang, Hua-Xing ;Luo, Cheng-Cai ;Zhao, Wen-Na ;Han, Lei
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 103 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.002 A Ê R factor = 0.041 wR factor = 0.116 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the structure of the title compound, C~15~H~13~ClN~2~OS, the dihedral angle between the two aromatic ring planes is 30.46 (8)°. Intermolecular N—H...S hydrogen bonds link the molecules into dimeric units which are stacked along [010].
The crystal structure of the title compound, C 14 H 17 ClN 2 OS 2 , is stabilized by intermolecular N-HÁ Á ÁS hydrogen bonds and stacking interactions.
In the title compound, C~20~H~15~ClN~4~, the two benzene rings form dihedral angles of 30.95 (9) and 70.69 (6)° with the triazole ring, and the dihedral angle between the triazole and the pyridine rings is 43.38 (8)°. Intermolecular C—H...N hydrogen bonds are observed in the crystal structure.
The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.