Methyl 3-[(Z)-1-(thiazol-2-yl)ethylidene]dithiocarbazate
✍ Scribed by Chen, Zhong-Yuan ;Wu, Guo-Qiang ;Jiang, Fen-Xiang ;Tian, Yu-Liang ;Shan, Shang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 269 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 20 H 12 N 2 OS, was synthesized by mixing 2,4-dichlorobenzaldehyde, ethyl chloroacetate and tetrahydropyrimidine-2-thione in ethanol. The dihedral angle between the naphthalene plane and the heterocyclic ring system is 9.3 (3) .
In the molecule of the title compound, C 21 H 18 N 4 O 2 S, all of the rings are individually planar. In the crystal structure, the molecules are linked by intermolecular N-HÁ Á ÁO hydrogen bonds, forming an infinite chain.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.040 wR factor = 0.116 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.