The title compound, C 15 H 15 NO 4 , was synthesized by acylation of methyl l-2-amino-3-phenylpropanoate with furan-2carbonyl chloride at room temperature. In the crystal structure, intermolecular N-HÁ Á ÁO hydrogen bonds link the molecules into extended chains parallel to the b axis.
Methyl 2-(4-methylphenylsulfonamido)-3-phenylpropanoate
✍ Scribed by Yin, Ping ;Hu, Mao-Lin ;Xiong, Jing ;Yan, Xiao-Wei
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 900 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, C 17 H 19 NO 4 S, has two independent molecules in the asymmetric unit linked by an N-HÁ Á ÁO hydrogen bond. The principal difference between them lies in the relative orientations of the two aromatic rings. These are inclined at an angle of 3.70 (3) in one molecule but at 58.41 (12) in the other. N-HÁ Á ÁO hydrogen bonds form zigzag chains down the a axis and these chains are further stabilized by weak C-HÁ Á ÁO interactions, forming a network structure.
Related literature
For general background, see Patani & Lavoie (1996) and Yan et al. (2007). For related structures, see Ziemer et al. (2001),
📜 SIMILAR VOLUMES
As part of our ongoing studies of metal coordination complexes with multidentate ligands (Tai et al., 2005), the synthesis and structure of the title compound, (I), is reported. Two O-monodentate ligands and two water molecules are attached to the calcium atom, resulting in a distorted CaO 4 tetrah
In the title compound, C 28 H 27 N 3 O 3 , the pyrazolone ring and the N atom of the 2-amino-3-phenylpropanoate group are essentially coplanar. The compound is in an enamine-keto form and its structure is stabilized by one strong intramolecular N-HÁ Á ÁO hydrogen bond.