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Methoxyphenylthiotrimethylsilylmethyllithium a convenient reagent for the homologation of carbonyl compounds

✍ Scribed by Steven Hackett; Tom Livinghouse

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 236 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91070-6

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✦ Synopsis

A facile homologation procedure for the conversion of carbonyl compounds into ketene-O,S-acetals is described. These intermediates are readily converted into ketene-O-silyl,S-acetals, thioesters, and carboxamides.

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