๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Method of calculating equilibrium constants in a homologous series

โœ Scribed by W.R. van Wijk; M.W. Geerlings

Publisher
Elsevier Science
Year
1962
Tongue
English
Weight
479 KB
Volume
17
Category
Article
ISSN
0009-2509

No coin nor oath required. For personal study only.

โœฆ Synopsis

At&met-A

method is given to calculate equilibrium constants of higher members in a homologous series. The equilibrium constant of one of them must be known as a function of temperature at the operating pressure. Further, the boiling temperature at this operating pressure is required for all components and, also, a relationship between the latent heats of vaporization of the various members such as, for instance, constant latent heat per unit of mass. Within these limitations the method is rigorously valid.

In a second article a correlation formula particularly suitable for use on digital computers will be given. The formula is based on the theory developed in the present article.

๐Ÿ“œ SIMILAR VOLUMES

The exponents method for calculating equ
The exponents method for calculating equilibrium concentrations of complex species in solution
โœ Frederico F. Campos; John S. Rollett ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 820 KB

The exponents method for calculating the concentrations of species in multimetal-multiligand systems is introduced. This method uses the Newton-Raphson method with restricted step iteration, which guarantees a monotonically decreasing objective function. Variable transformation and scaling are perfo

Calculating affinity constants of substr
Calculating affinity constants of substrate mixtures in a chemostat
โœ Th. Bley; W. Babel ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 137 KB ๐Ÿ‘ 1 views

An "oversimplified" method for calculating affinity constants in substrate mixtures is evaluated concerning its validity. It is shown that the redl affinity to the mixture as determined by using the correct method is always higher, i.e., leads to a lower affinity constant, as compared to the wrong m

Evaluation of dead time calculation in l
Evaluation of dead time calculation in liquid chromatography using a linearization procedure for homologous series
โœ van Tulder, P. J. M. ;Franke, J. P. ;de Zeeuw, R. A. ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 769 KB

A mathematical method for the calculation of the dead time (tM) in HPLC was evaluated using a computer simulationapproach, in which artificial perturbations were introduced to simulated homolog retention times. The calculation was based on a modified and extended Grobler and Balisz (GB) method. Inve