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Method for Arylation of the Amino Group in N-Aminoazoles

โœ Scribed by O. V. Dyablo; A. F. Pozharskii; M. G. Koroleva

Book ID
110389217
Publisher
Springer US
Year
2002
Tongue
English
Weight
94 KB
Volume
38
Category
Article
ISSN
0009-3122

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

The reaction of o-amino aryl carboxylic
The reaction of o-amino aryl carboxylic acids with Grignard reagents. The unusual effect of the N-protecting group on aryl ketone formation
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The addition of Grignard reagents to the o-amino aryl carboxylic acids without any additive forms the tertiary carbinol as a major product. Unexpectedly, the aryl ketones are formed as the only isolated product if o-amino moiety of anthranilic acids is protected with Boc, trifluoroacetyl, and pivalo