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Methanophenazine: Structure, Total Synthesis, and Function of a New Cofactor from Methanogenic Archaea

✍ Scribed by Uwe Beifuss; Mario Tietze; Sebastian Bäumer; Uwe Deppenmeier

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
199 KB
Volume
39
Category
Article
ISSN
0044-8249

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On the total synthesis of (S)-methanophe
On the total synthesis of (S)-methanophenazine and the formal synthesis of (R)-methanophenazine from a common precursor
✍ Uwe Beifuss; Mario Tietze 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 79 KB

Methanophenazine is a new cofactor from methanogenic archaea. (S)-Methanophenazine has been synthesized from three building blocks, i.e. 2-hydroxy-phenazine, ethyl (R)-3-methylglutarate and (E,E)farnesyl acetone; a stereodivergent approach from ethyl (R)-3-methylglutarate warrants the formal synthes