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Methanol and ethanol oxidation by chromium(VI) in aqueous perchloric acid

✍ Scribed by Enrique Pérez-Benito; Elvira Rodenas

Publisher
Springer
Year
1993
Tongue
English
Weight
433 KB
Volume
18
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of oxidation of d-glucopyranose 6-phosphate and d-ribofuranose 5-phosphate by chromium(VI) in perchloric acid media
✍ Kalyan Kali Sen Gupta; Shipra Sen Gupta; Subrata Kumar Mandal; Samarendra Nath B 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 359 KB

The kinetics of oxidation of D-glucopyranose 6-phosphate and D-ribofuranose 5-phosphate by chromium(V1) in perchloric acid media have been studied by U.V. spectroscopy. Each reaction is first order with respect to [chromium(VI)] and [substrate]. The reactions are acid-catalysed and accelerated by th